It's a bit of magic, let me try to explain )
Plugin places slices one-after-one keeping the specified stepover all the time (10 % in you case). If the next slice can't be placed to satisfy specifed stepover, it may be either still emitted or ignored.
If min stepover setting is 0.5, it means 10% * 0.5 = 5% stepover is ok too, keep this slice, otherwise drop it.
It works this way for stepover undershoot. Stepover overshoot is never allowed, new cutters cost money )
0.8-0.9 seems to be ok most of the times.
For some complicated shapes plugin may stop producing slices half-way, setting should be lowered to help him get thru.
For some shapes setting may affect profile accuracy in the corners (see attachment 0 and 1).
Unnecessary low value allows plugin to produce very thin slices here and there (see attachment 2 and 3)
In other words, leave it default and lower only in case of the problems :-)